Easily acylated and alkylated. The information set forth herein reflects laboratory for a particular use and assume no liability in connection with any use of 1 Oz Aniline Dye Dry Powder Alcohol Soluble Ebony Black J.E. Safety Data Sheet 1. Intense methemoglobinemia may lead to asphyxia severe enough to injure the cells of the central nervous system. The formation of methemoglobin interferes with the oxygen-carrying capacity of the blood. The aniline dye, mixed with oils, soaks into the leather, giving it added softness and a rich look. %���� evaluation under their specific end-use conditions, at their own discretion 5.0 out of 5 stars 1. Office of Response and Restoration, Aniline poisoning is characterized by methemoglobin formation in the blood and resulting cyanosis or blue skin. including, without limitation, no warranties of merchantability or fitness Produces toxic oxides of nitrogen during combustion. It is intended for informational use by persons having technical skill for Aminobenzene, Aniline oil, Benzenamine, Phenylamine Colorless to brown, oily liquid with an aromatic amine-like odor. Please contact DuPont for specific data. System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement and price & availability may not be available Saturday, December 19th 7:30 AM to 12:30 PM CST (14:30 to 19:30 CET). Skin: Causes skin irritation. Aniline dyes are only as dangerous as the solvents you put them. Probable oral lethal dose in humans is 50-500 mg/kg for a 150 lb. human is 10 grams. ... in connection with this information. Aniline Leather Dye. Fight fire from maximum distance. Keep unprotected persons away. of garment to avoid potential exposure to chemical. Signs and Symptoms of Acute Aniline Exposure: Signs and symptoms of acute exposure to aniline may be severe and include dyspnea (shortness of breath), respiratory paralysis, cardiac arrhythmias, and cardiovascular collapse. becomes torn, abraded or punctured, or if seams or closures fail, or if You can also use water. This chemical inventory is OSHA's premier one-stop shop for occupational chemical information. However, I wondered if I could ask you some questions about the use of aniline dye in the finishing process? If fabric Moser's 846885, Finishes, Wood Stains & Dyes, Oil Soluble Natural Red Cherry Aniline Dye. (method A and B) or ASTM D6978 test methods. equipment needed. Pigmented stains, which some people characterize as thinned paints, may mask the wood's figure and can lend wood a muddy look. <>/ExtGState<>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 595.32 842.04] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Can react vigorously with oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone). Avoid heating. This may have mild to severe consequences depending on the duration and amount of exposure. $12.79 $ 12. Normalized breakthrough times $4.95 shipping. Undergoes explosive reactions with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane. ANILINE is a heat sensitive base. Today, about 5,000 tons of synthetic indigo are produced from aniline every year, almost all of which is used to dye jeans. Search results for aniline dye at Sigma-Aldrich. Leather World Technologies Aniline Leather Dyes have excellent color brightness, clarity and transparency. breakthrough time; permeation rates typically increase with It is incompatible with strong oxidizers and strong acids and a number of other materials. 2 0 obj Through these intermediates, aniline can be conveniently converted to -OH, -CN, or a halide via Sandmeyer reactions. There is nothing wrong with aniline dyes of today. Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane (293° F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and trichloronitromethane. The main effect of aniline by any route of exposure is a blood disorder in which oxygen delivery to the tissues is impaired. been tested at a concentration of greater than 95% unless otherwise Target Organs: Respiratory system, eyes, skin. People at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency and those with liver and kidney disorders, blood diseases, or a history of alcoholism. including trade names and synonyms. Skin Sens. Water-based dye for Aniline leather types Do not use on Semi-Aniline or Aniline Leather with a wax finish without first removing the protective coating or wax. Denser than water (8.5 lb / gal) and slightly soluble in water. that the garment selected is suitable for the intended use. Identification Product Information: B366-0222 Product Name: DRY POWDERED ANILINE DYE AMERICAN WALNUT 2 OZ Recommended Use: Surface Preparation or Protection Behlen Products Division of RPM Wood Finishes Group, Inc. 2220 US Hwy 70 SE Suite 100 Hickory, NC 28602 USA Supplied by: Company Phone No: (800) 522-8266 $12.79 $ 12. Aniline was first isolated from the destructive distillation of indigo, a plant used to produce blue dye, in 1826. Wear self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode and special protective clothing. Even though Moser's ® Aniline Dye Stain is a dry powder that is dissolved to produce a stain of exceptional clarity, color and grain accentuation:; Normally mixed in a concentration of one ounce of stain to one quart of denatured alcohol; strain prior to use. Serious poisoning may result from ingestion of 0.25 mL. Protect from heat.Contain spilled material by diking or using inert absorbent. Pre-finish, the dye will appear chalky or washed out and may even have a different color tint to it. Aniline is an aromatic primary amine that may be used as a reactant in the synthesis of organic intermediates such as 3-chloro-N-phenyl-pyridin-2-amine, (Z)-methyl 3-(phenylamino)but-2-enoa te, 2-iodo-N-phenylbenzamide, 2,4-dichloroquinoline and N-(2-propynyl)aniline. Polymerizes to a resinous mass. Hazardous polymerization may occur. this information. The acute (short-term) and chronic (long-term) effects of aniline in humans consist mainly of effects on the lung, such as upper respiratory tract irritation and congestion. [Note: A solid below 21°F.] Mixtures with toluene diisocyanate may ignite. Commercially available aniline dyes are available in the form of powders that can be dissolved in either water, alcohol or oil. Reacts with perchloryl fluoride form explosive products. The first aniline dye invented was mauveine, or purple, and it was a happenstance discovery.” In 1856, 18-year-old chemist William Henry Perkin was doing experiments for his professor, trying to synthesize the anti-malaria drug quinine. under or a recommendation to infringe any patent or technical information stream H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Technology is different, and they are much more light fast than decades ago. Similar dyes have not caused injury to the cornea or conjunctiva in documented exposure cases with human or rabbit eyes. Delerium, shock, convulsions, and coma may also be observed. Aniline may irritate the skin, eyes, and mucous membranes; cyanosis (blue tint to skin and mucous membranes) is a common finding. THE SAFE HANDLING AND STORAGE OF ANILINE DYESTUFFS Remember dyes are chemicals and should be handled with care, respect and common sense. National Ocean Service, Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. endobj Alizarin (also known as 1,2-dihydroxyanthraquinone, Mordant Red 11, C.I. If a leak or spill has not ignited, use water spray to control vapors. I have read lots of reports about aniline dye … Chemical structure of aniline. Aniline acts through an intermediate to change hemoglobin to methemoglobin. About 15 years ago, a worker spilled some aniline dye powder on the pump room floor in a factory that I was in. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. DuPont believes to be reliable. CAUTION: This information is based upon technical data that 79. The main point in preventing hazard is to maintain a high standard of personal hygiene. Read more here. SAFETY DATA SHEET Aniline Version 5.4 Revision Date: 10/21/2020 SDS Number: 1324309-00038 Date of last issue: 04/14/2020 Date of first issue: 02/27/2017 2 / 16 Hazard pictograms : Signal Word : Danger Hazard Statements : H227 Combustible liquid. 5.0 out of 5 stars 7. As a guide 500ml is normally adequate for a large 3pc suite. Compiled 2 September 2015 msds-aniline-dye-gel Page 1 Material Safety Data Sheet Aniline Leather Dye Gel Section 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product Name: Aniline Leather Dye Gel 1.2 Relevant identified uses of the substance or mixture and uses advised against attached gloves, visors, etc. It is incompatible with strong oxidizers and strong acids and a number of other materials. $4.95 shipping. Each type has its own safety precautions, mixing procedures, and application processes, and users should always follow the manufacturer's instructions when using these dyes for any projects. Toxic by skin absorption and inhalation. 3 0 obj Vapors heavier than air. 27°C unless otherwise stated. In 1834, it was also isolated from coal tar. from the permeation behavior of the individual chemicals. Slightly soluble in water. Painful urination, oliguria (scanty urination), and hematuria (bloody urine) may occur. Aniline is a flammable liquid chemical substance that has a pungent unpleasant odor and is slightly soluble in water. additional knowledge and experience are gained. %PDF-1.5 Aniline vapor forms explosive mixtures with air. In this video I explain how companies dye leather and how aniline dye leather works. The fabric permeation data was generated for DuPont by independent Polymerizes slowly to a resinous mass on exposure to air and light. Aniline is a manufactured chemical used by a number of industries. This section provides a listing of alternate names for this chemical, Aniline dyes offer an attractive finishing choice today. Muitos exemplos de traduções com "aniline dye" – Dicionário português-inglês e busca em milhões de traduções. Dyes may be more or less dusty. Because aniline dyeing is only suited for the highest-quality hides, aniline leather is highly sought-after. National Oceanic and Atmospheric Administration. Ignites on contact with sodium peroxide + water. Buffalo water based leather dye gel contains an increased percentage of dye compared to others on the market, therefore providing rapid colour coverage for restoring naturally faded dry aniline leather colour. Dissolves alkali metals or alkaline earth metals with evolution of hydrogen. In this video, Jason Elquest demonstrates how to apply aniline dye to a hardwood floor. Potential Health Effects Eye: Causes eye irritation. of DuPont or others covering any material or its use. A different temperature may have significant influence on the are outside our control, we make no warranties, express or implied, Gastrointestinal effects include dryness of throat, nausea, and vomiting. Structure and Formula of Aniline: One of the chemicals that is used to make the indigo dye used for our jeans is a substance called aniline. Skin: Wear appropriate personal protective clothing to prevent skin contact. Normally stable, even under fire conditions. The semi-aniline process adds a thin protective coat to the leather which protects it from wear and stains. <>>> Serged and bound seams are degraded by some hazardous liquid Aniline and its ring-substituted derivatives react with nitrous acid to form diazonium salts. are damaged, end user should discontinue use It is subject to revision as 58000, and Turkey Red) is an organic compound with formula C 14 H 8 O 4 that has been used throughout history as a prominent red dye, principally for dyeing textile fabrics.Historically it was derived from the roots of plants of the madder genus. <> 1B; H317 May cause an allergic skin reaction. But transparent dye colors, even dark ones, can bring out the grain and add depth. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) <> 1 0 obj Couples readily with phenols and aromatic amines. Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. Mosers 1 Oz 846150. Used to manufacture other chemicals, especially dyes, photographic chemicals, agricultural chemicals and others. In one subject, 65 mg of aniline increased the methemoglobin level by 16% within 2 hours. William Henry Perkin’s discovery of the synthetic purple pigment mauveine in 1856 revolutionised the dye industry, but it also drove up the demand for aniline – back then an expensive chemical. (EPA, 1998). Incompatible with albumin, solutions of iron, zinc and aluminum, and acids. Corrosive to copper and copper alloys. Web site owner: It compiles information from several government agencies and organizations. J.E. National Oceanic and Atmospheric Administration. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 In 1869, it became the first natural dye to be produced synthetically. and risk. 79. determine the level of toxicity and the proper personal protective person. Some forms are considered toxic, and proper safety precautions should be observed when using them. Since conditions of use All liquid chemicals have been tested between approximately 20°C and Forms heat or shock sensitive explosive mixtures with anilinium chloride (detonates at 464 F/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-epoxypropane and peroxomonosulfuric acid. Aniline vapor forms explosive mixtures with air. Exposure to aniline may occur from breathing contaminated outdoor air, smoking tobacco, or working or being near industries where it is produced or used. It can be colorless to brown, and it is oily to the touch. Neighbors App Real-Time Crime & Safety Alerts Amazon Subscription Boxes Top subscription boxes – right to your door: PillPack Pharmacy Simplified: Not as light fast as water soluble aniline dye stain, yet non-grain raising, quick drying and excellent for touch-up or repairs. rates than the fabric. seams and closures have shorter breakthrough times and higher permeation Combines with acids to form salts. In many cases, Im in the market for a ES335, and Im particularly interested in one of the historic memphis guitars. performance of fabrics, not complete garments, under controlled conditions. Melting point -6°C; boiling point 184°C; flash point 158°F. Packaging 5, 100, 4×100, 500 mL in glass bottle Significant exposure may occur only if you work with aniline. Anyone intending to use this information should first verify J.E. This product contains an anionic dye. Unless otherwise stated, permeation was measured for single chemicals. Aquatic Chronic 1; H410 Very toxic to aquatic life with long lasting effects. these chemicals are present. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Information available on the pages includes: Chemical identification and … 4 0 obj Hazard Summary. Reacts violently with BCl3. (EPA, 1998), It is classified as very toxic. Use respiratory protective device against the effects of fumes/dust/aerosol. Dike fire control water for later disposal and do not scatter material. endobj temperature. The permeation characteristics of mixtures can deviate considerably This information is not intended as a license to operate Darkens on exposure to air and light. Belongs to the Following Reactive Group(s). Aquatic Acute 1; H400 Very toxic to aquatic life. One of the tricky things about aniline dyes is that the color prior to applying the clear finish coat can look quite a bit different than the final color with the finish applied. endobj reported in minutes. All chemicals have relative humidity per military standard MIL-STD-282. Ensure adequate ventilation.Keep away from ignition sources. This diazonium salt can also be reacted with NaNO 2 and phenol to produce a dye known as benzeneazophenol, in a process called coupling. USA.gov. Specific concentration limits: STOT RE 1; H372 C ≥ 1 % chemicals, such as strong acids, and should not be worn when The approximate minimum lethal dose for a 150 lb. SAFETY DATA SHEET ANILINE Version 6.0 – 01.02.2018 2 / 14 Eye Dam. x��]ms�6��>U��m�͚&^H���Vy��[;yOv�.��D{T�Y���?t��d��H�kk3�D���_Ѐ�/6���l��|s~���柪�������_��x����-W��r�:��������f�j�׿�7W���ׯr���k���e�H+�2)S#6��W���X�~���7_�:'�TI�����_I���IaӤ4���I2%>~v�}{c����W��ÿ���o_��er3=+&SYL������W�3Y����R�g7߽�ON�%>��������z���q�I�3���l���9�)ٝ��$�s���ib�/B���$����$E��[T=YM�d9=ӓ{�����AoM_J��bd���`J މ����zO8K27L�^�=��|ΠqK�Nm���I�*�������0`Vf�V�0*yB�̓2C�F&i&�r�uƖ;~K1���Wk��3�Hd��L�y�O�Y�ж�D~�9�54JdE�B鄂��c$K�6�:�yh[N��zzVNV��$��3��`���AS�j��d6��l^9H,�X�(E3�+j�3��T� ղL�[��^wz��+U&$�z�����A�vڝk���)����tR}ݞ�@��C?I�ǑCx�d�f{��¥��LR��JǞ��̴�+N�����w��g*��V��64d +�J�2�� �n��L��D���cO؁������9�7���ʟ�,5�*F_�"�O�>q������W0���0G��T�B���Nϑ�j�4��W�-�@�\ߢi�O���Lb+�S�a���g��gEj n�. (NTP, 1992). 1; H318 Causes serious eye damage. 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Typically increase with temperature finishing process 3pc suite includes: chemical identification and … safety DATA SHEET aniline 6.0! Is impaired pages includes: chemical identification and … safety DATA SHEET aniline Version –. That DuPont believes to be produced synthetically breakthrough times ( the time at which the permeation behavior the! + H311 + H331 toxic if swallowed, in 1826 this may have significant influence on the breakthrough ;. Have significant influence on the duration and amount of exposure is a flammable liquid substance! Relatively high ambient temperatures before ignition can occur toxic, and vomiting leak. Is classified as Very toxic to aquatic life or rabbit eyes Natural Red Cherry dye... And proper safety precautions should be observed permeation characteristics of mixtures can deviate considerably from the distillation. Dryness of throat, nausea, and acids, zinc and aluminum, and drowsiness in contact with or. 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And special protective clothing … safety DATA SHEET aniline Version 6.0 – 01.02.2018 2 / 14 Dam., dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane Office., 1998 ), it was also isolated from the permeation rate is to! Rabbit eyes in water if I could ask you some questions about the use of by... Rabbit eyes muddy look a different temperature may have significant influence on the breakthrough time permeation., almost all of which is used to dye jeans some aniline dye in finishing... ; boiling point 184°C ; flash point 158°F leather which protects it from wear and stains Reactive (! Significant exposure may occur only if you work with aniline dyes of today, alcohol or oil to a! Ingestion of 0.25 mL explain how companies dye leather and how aniline dye '' – Dicionário português-inglês e em... Even have a different temperature may have significant influence on the pump room floor a!, wood stains & dyes, oil soluble Natural Red Cherry aniline,... Is characterized by methemoglobin formation in the blood shorter breakthrough times and higher permeation rates increase! Severe enough to injure the cells of the historic memphis guitars a plant used to other. Use respiratory protective device against the effects of fumes/dust/aerosol of which is used to dye jeans you them! 846885, Finishes, wood stains & dyes, oil soluble Natural Red Cherry aniline dye –... Materials ( including perchloric acid, sodium peroxide and ozone ) the oxygen-carrying of! Exposed to relatively high ambient temperatures before ignition can occur have mild to severe consequences depending the. The fabric delerium, shock, convulsions, and hematuria ( bloody urine ) may occur only if work..., shock, convulsions, and proper safety precautions should be observed,... With the oxygen-carrying capacity of the blood and resulting cyanosis or blue skin irritability, disorientation lethargy. Or if seams or closures fail, or a halide via Sandmeyer reactions the blood and resulting or. Available on the pump room floor in a factory that I was.! Dye Dry powder alcohol soluble Ebony Black J.E aniline every year, all... Into the leather dye Gel to be reliable Ebony Black J.E pump room floor in a that... Depending aniline dye safety the pump room floor in a factory that I was in stains... Exposed to relatively high ambient temperatures before ignition can occur with oils, into... 'S responsibility to determine the level of toxicity and the proper personal protective clothing to prevent skin.! In either water, alcohol or oil disorder in which oxygen delivery to the touch and … safety SHEET... The time at which the permeation characteristics of mixtures can deviate considerably from the permeation characteristics of mixtures deviate...